Pál Rakonczai, Institute of Mathematics, Probability Theory and Statistics, Budapest Abstract In the field of environmental studies or financial mathematics the simultaneous appearance of peaks are subject of major interest: either the joint extremes of several gauges or stocks, or extremes of the main phenomena and high values in their explanatory variables e.g. flood peaks and high rainfall, peaks of oil and other commodity stock prices may define these problems. Mathematical statistics offers sophisticated tools for examining the dependence structure of such extreme events. An important one of those providing a way to study the dependence structure of high values separately from the marginal distributions is the so-called copula approach nowadays especially widely used in the aforesaid areas. To find the appropriate copula model necessitates the elaboration of finely tuned goodness-of-fit (GOF) statistics. Though there are known measures, but more often then not they are effective only in the two dimensional case, and they are not really suitable to the above-mentioned problem of the dependence of the multivariate extremes. We were confronted with the need to work out more appropriate methods when studying river flow series in Hungary. We were able to increase substantially the sensitivity of GOF evaluation by introducing appropriate weights into the test-statistics, and in the end it helped to choose the model that provided reliable long term estimates for flood risk. The main approaches are based on the multivariate probability integral transformation of the joint distribution, which reduces the multivariate problem to one dimension. As a finer assessment of fit of the dependence structure we also build a test-statistic analogous to the previous one but based on a non-parametric estimator of the copula density. The applications of the methods are illustrated on financial and river flow data. Keywords: Copula models, Goodness-of-Fit, Probability Integral Transformation, Kernel estimations, River flow series, Stock prices